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研究了表面施加含有不同量Y2O3的Cr2O3和Al2O3薄膜对Cr2O3形成合金Fe25Cr在1000℃、104PaO2环境中高温氧化的作用.结果发现含Y氧化物薄膜明显降低了Cr2O3层的生长速度,而且含Y复合氧化物薄膜的作用大于单一Y2O3薄膜.此时,Cr2O3层表面形貌发生了较大的变化.间接证据表明Cr2O3的生长机制由阳离子向外扩散为主转变为阴离子向内扩散为主.通过表面施加含Y的氧化物薄膜产生了全面的“活性元素效应”
The effect of surface Cr2O3 and Al2O3 films containing different amounts of Y2O3 on the oxidation of Cr2O3-forming alloy Fe25Cr at 1000 ℃ and 104PaO2 was studied. As a result, it was found that the Y oxide-containing thin film significantly reduced the growth rate of the Cr2O3 layer, and the effect of the Y-containing composite oxide thin film was greater than that of the single Y2O3 thin film. At this point, Cr2O3 layer surface morphology has undergone major changes. Indirect evidence indicates that the growth mechanism of Cr2O3 mainly changes from the outward diffusion of cations to the inward diffusion of anions. The overall “active element effect” results from the application of a Y-containing oxide film on the surface