【摘 要】
：
The reaction of silyl enol ethers (la-le) with perfluoroalkyl iodides (2f-2k) initiated withsodium dithionite was studied, α-Perfluoroalkyl ketones (3) were s
【出 处】
：
Chinese Journal of Chemistry
论文部分内容阅读
The reaction of silyl enol ethers (la-le) with perfluoroalkyl iodides (2f-2k) initiated withsodium dithionite was studied, α-Perfluoroalkyl ketones (3) were synthesized in excellent yield bythis method, α,β-Unsaturated fluorinated ketones (4) were obtained easily by dehydrofluorinationof the α-perfluoroalkyl ketones. A radical mechanism was proposed.
The reaction of silyl enol ethers (la-le) with perfluoroalkyl iodides (2f-2k) initiated with sodium dithionite was studied, α-Perfluoroalkyl ketones (3) were synthesized in excellent yield bythis method, were obtained easily by dehydrofluorinationof the α-perfluoroalkyl ketones. A radical mechanism was proposed.
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