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受前行化学反应和平行化学反应的示差脉冲极谱电流理论已有论述。本文报道了受扩散和后行化学反应(EC过程)控制的示差脉冲极谱电流方程式并用实验进行了验证,应用该理论求得的动力学参数与文献值一致。 1 理论 讨论的反应如(1)、(2)式所示
The theory of differential pulse polarography current which has been subjected to the chemical reactions in parallel and parallel to chemical reactions has been discussed. In this paper, the differential pulse polarographic current equation controlled by diffusion and chemical reaction (EC process) is reported and validated experimentally. The kinetic parameters obtained by this theory are consistent with the literature values. 1 The theoretical discussion of the reaction as (1), (2) shows