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Brazing of Ti3AI alloys with the filler metal Cu-P was carried out at 1173-1273 K for 60-1800 s. When products are brazed, the optimum brazing parameters are as follows: brazing temperature is 1215-1225 K; brazing time is 250-300 s. Four kinds of reaction products were observed during the brazing of Ti3AI alloys with the filler metal Cu-P, i.e., Ti3AI phase with a small quantity of Cu (Ti3AI(Cu)) formed close to the Ti3AI alloy; the TiCu intermetallic compounds layer and the Cu3P intermetallic compounds layer formed between Ti3AI(Cu) and the filler metal, and a Cu-base solid solution formed with the dispersed Cu3P in the middle of the joint. The interfacial structure of brazed Ti3AI alloys joints with the filler metal Cu-P is Ti3AI/Ti3AI(Cu)/TiCu/Cu3P/Cu solid solution (Cu3P)/Cu3P/TiCu/Ti3AI(Cu)/Ti3AI, and this structure will not change with brazing time once it forms. The thickness of TiCu+Cu3P intermetallic compounds increases with brazing time according to a parabolic law. The activation energy Q and the growth velocity K0 of reaction layer TiCu+Cu3P in the brazed joints of Ti3AI alloys with the filler metal Cu-P are 286 kJ/mol and 0.0821 m2/s, respectively, and growth formula was y2=0.0821exp(-34421.59/T)t. Careful control of the growth for the reaction layer TiCu+Cu3P can influence the final joint strength. The formation of the intermetallic compounds TiCu+Cu3P results in embrittlement of the joint and poor joint properties. The Cu-P filler metal is not fit for obtaining a high-quality joint of Ti3AI brazed.
Brazing of Ti3AI alloys with the filler metal Cu-P was carried out at 1173-1273 K for 60-1800 s. When products are brazed, the optimum brazing parameters are as follows: brazing temperature is 1215-1225 K; brazing time is 250 -300 s. Four kinds of reaction products were observed during the brazing of Ti3AI alloys with the filler metal Cu-P, ie, Ti3AI phase with a small quantity of Cu (Ti3AI (Cu)) formed close to the Ti3AI alloy; the TiCu intermetallic compound layer and the Cu3P intermetallic compound layer formed between Ti3AI (Cu) and the filler metal, and a Cu-base solid solution formed with the dispersed Cu3P in the middle of the joint. metal Cu-P is Ti3AI / Ti3AI (Cu) / TiCu / Cu3P / Cu solid solution (Cu3P) / Cu3P / TiCu / Ti3AI (Cu) / Ti3AI, and this structure will not change with brazing time once it forms. The thickness of TiCu + Cu3P intermetallic compounds increases with brazing time according to a parabolic law. The activ ation energy Q and the growth velocity K0 of reaction layer TiCu + Cu3P in the brazed joints of Ti3AI alloys with the filler metal Cu-P are 286 kJ / mol and 0.0821 m2 / s, respectively, and growth formula was y2 = 0.0821exp -34421.59 / T) t. Careful control of the growth for the reaction layer TiCu + Cu3P can influence the final joint strength. The formation of the intermetallic compounds TiCu + Cu3P results in embrittlement of the joint and poor joint properties. The Cu-P filler metal is not fit for obtaining a high-quality joint of Ti3AI brazed.