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用循环伏安法测定了离子在水-异硫氰酸烯丙脂(AIT)体系中的标准转移Gibbs能△_o~w G_(tr,i)~0。对含有AIT的混合溶剂的研究,发现了一系列电位窗比较宽的水/有机溶剂体系,讨论了溶剂效应对△_o~w G_(tr,i)~0的影响。
The standard transfer Gibbs energy △ _o ~ w G_ (tr, i) ~ 0 of ions in water-isothiocyanate allyl ester (AIT) system was determined by cyclic voltammetry. A series of water / organic solvent systems with a wide potential window were found for the mixed solvent containing AIT. The effect of solvent effect on Δ_o ~ w_ (tr, i) ~ 0 was discussed.