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与[C_(12)H_(25)N~+(CH_3)_2CH_2]_2·2Br~-(简记为 C_(12)-2-C_(12)·2Br)/C_(12)H_(25)SO_4Na(SDS)混合水溶液相比,随着联接链上乙氧基团(E)数目增加,[C_(12)H_(25)N~+(CH_3)_2]_2C_2H_4(OC_2H_4)_n·2Br~-(简记为 C_(12)-2-E_n-C_(12)·2Br,n=2,3)与 SDS 混合水溶液澄清区域明显增大,C_(12)-2-E_3-C_(12)·2Br/SDS 混合胶团化过程中二组分产生了协同效应,理论预测在澄清区域所能达到的最小临界胶团总浓度(cmc_(T.mim))=0.0339mmol·L~(-1),对应的 SDS 在溶液体相中的摩尔分数(x_2~(*))=0.447.当水溶液体相中 SDS 摩尔分数(x_2)=0.5时,混合胶团总聚集数(N_T)=36,混合胶团中 SDS 的摩尔分数(x_2~M)=0.43。
And C_ (12) H_ (25) N ~ + (CH_3) _2CH_2] _2 · 2Br ~ (abbreviated as C_ (12) -2-C_ (12) · 2Br) / C_ (12) H_ (C_ (12) H_ (25) N ~ + (CH_3) _2] _2C_2H_4 (OC_2H_4) _n · 2Br ~ - as the number of ethoxy groups (E) (12) -2-E_n-C (12) · 2Br, n = 2, 3) in the mixed aqueous solution of SDS with C12 The synergistic effect of the two components during the 2Br / SDS mixed micelle formation was predicted theoretically. The total critical micelle concentration (cmc_ (T.mim) = 0.0339mmol·L -1) , The corresponding mole fraction of SDS in solution phase (x_2 ~ (*)) = 0.447. When the SDS molar fraction (x_2) = 0.5 in the aqueous phase, the total aggregation number (N_T) of mixed micelles = 36, the molar fraction of SDS in mixed micelles (x_2 ~ M) = 0.43.