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六硝基六氮杂异伍兹烷(HNIW)可与二甲基甲酰胺(DMF)形成稳定的分子加合物(两者分子比为1:2)。首次报道了该加合物的晶体结构、晶体学数据和结构参数。该加合物为无色透明片状晶体,属三斜晶系,空间群Pi。在该加合物中,HNIW与DMF分子以范德华力结合,彼此间不存在氢键或偶极作用。
Hexanitrohexaazaisowurtzitane (HNIW) forms a stable molecular adduct with dimethylformamide (DMF) at a molecular ratio of 1: 2. For the first time reported the adduct crystal structure, crystallographic data and structural parameters. The adduct is a colorless and transparent lamellar crystal, belonging to the triclinic system and space group Pi. In this adduct, HNIW binds to DMF molecules with van der Waals forces with no hydrogen bonding or dipole interaction with each other.