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目前,Mo-S化合物的化学,特别是以多硫基为配体的铟硫化合物的化学是一个活跃的研究领域。这里我们报道含S_2~(2-)、S_4~(2-)两种多硫基的二核钼原子簇化合物〔Et_4N〕_2〔Mo_2O_2(S_2)(S_4)(u_3-S)_2]的合成和单晶结构。
At present, the chemistry of Mo-S compounds, especially the polythio-based compounds of indium-sulfur compounds, is an active area of research. Here we report the synthesis of a binary nuclear molybdenum cluster [Et4N] _2 [Mo_2O_2 (S_2) (S_4) (u_3-S) _2] containing two kinds of S_2 ~ (2-) and S_4 ~ (2-) And single crystal structure.