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5. Stereochemistry and solid-state circular dichroism spectroscopy of eight-coordinate chiral lanthanid

Stereochemistry and solid-state circular dichroism spectroscopy of eight-coordinate chiral lanthanid

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：nicenic

【摘 要】

：

Eight-coordinate chiral lanthanide complexes [Eu(dbm)3LRR](1),[Eu(dbm)3LSS](2) and [Tb(dbm)3LRR](3)(LRR/LSS =(-)-/(+)-4,5-pineno-2,2’-bipyridine,Hdbm = dibenzo

【作 者】

：

Nan Zhou (1)  ShiGang Wan (1) 

【机 构】

：

1.StateKeyLaboratoryofPhysicalChemistryofSolidSurfaceandDepartmentofChemistry

【出 处】

：

中国科学：化学英文版

【发表日期】

：

2009年11期

【关键词】

：

eight-coordinate lanthanide complex Β-DIKETONE CHIRAL bipyridine crystal structu 

【基金项目】

：

Supported by the National Natural Science Foundation of China (Grant Nos. 20773098 & 20973136),the Innovation Foundation of Xiamen University (Series 2) (Grant No. XDKJCX20061027)

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论文部分内容阅读

Eight-coordinate chiral lanthanide complexes [Eu(dbm)3LRR](1),[Eu(dbm)3LSS](2) and [Tb(dbm)3LRR](3)(LRR/LSS =(-)-/(+)-4,5-pineno-2,2’-bipyridine,Hdbm = dibenzoylmethane) were synthesized stereoselectively,which were characterized by UV-vis,CD spectra and

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