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研究了氯化铈表面化学处理对于SiCp/2024 Al铝基复合材料在含氯离子介质中的耐蚀性的影响.研究结果表明,氯化铈表面化学处理使该复合材料的点蚀电位(Ep)发生显著正移(P <0.01).处理后点蚀电位与自腐蚀电位之差(ΔE = Ep- Ecorr)也显著增大.而随着铝基复合材料中SiCp 的体积分数的增加,表面处理的效果显著下降.交流阻抗谱和电流-时间谱测试表明,经过氯化铈化学处理的铝基复合材料相比未处理前在0.1 m ol/LNaCl溶液中浸泡不易出现局部破坏和微孔腐蚀现象.
The effect of surface chemical treatment of cerium chloride on the corrosion resistance of SiCp / 2024Al aluminum matrix composites in chloride ion-containing media was investigated. The results show that the surface chemical treatment of cerium chloride makes the pitting potential (Ep) of the composite significantly positive shift (P <0.01). After treatment, the difference between the pitting potential and the corrosion potential (ΔE = Ep-Ecorr) also increases significantly. With the increase of volume fraction of SiCp in aluminum matrix composites, the effect of surface treatment decreased significantly. AC impedance spectroscopy and current-time spectroscopy tests show that the cerium chloride-treated aluminum-based composites are less susceptible to partial destruction and micropore corrosion when soaked in 0.1 mol / L NaCl solution than before.