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本文合成了含μ_3-O的三核铁甲酸配合物[Fe_3(μ3-O)(μ-O_2CH)_6(H_2O)_2(O_2GH)]·2H_2O.进行了元素分析、红外与Raman光谱、核磁与顺磁共振波谱分析和磁化率测定,并作了配合物的X射线单晶结构分析。比较了同系物的结构,且讨论了波谱及其它性能的研究结果。
In this paper, the tri-nuclear ferrocene complex [μ_3-O (μ_2O_2CH) _6 (H_2O) _2 (O_2GH)] · 2H_2O containing μ_3-O was synthesized and characterized by elemental analysis, IR and Raman spectroscopy, Paramagnetic resonance spectroscopy and magnetic susceptibility determination, and the X-ray single crystal structure analysis of the complex. The structures of homologues were compared and the results of spectroscopy and other properties were discussed.