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本文报道了标题中所指的配合物固体和单晶的制备，测定了ＩＲ，ＵＶ－Ｖｉｓ光谱以及该配合物在ＣＨ３ＣＮ和ＤＭＦ中的光化学性质．采用单晶Ｘ射线衍射测定了该配合物的结构，它属于单斜晶系，空间群Ｐ２１／ｎ，测定了固体配合物在ＣＨ３ＣＮ和ＤＭＦ中的量子产率Φ（ＮＣＳ），并讨论了光反应机制．
In this paper, we report the preparation of complex solids and single crystals in the title. The IR, UV-Vis spectra and the photochemical properties of the complex in CH3CN and DMF have been measured. The structure of the complex was determined by single crystal X-ray diffraction. It belongs to the monoclinic space group P21 / n, and the quantum yield Φ (NCS) of the solid complex in CH3CN and DMF was measured. Reaction mechanism.