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{[Eu(OOCCH2NHCOCH2NH3)2(H2O)2]·(ClO4)3·2H2O}2,Mr = 1572,P21/n,a=12. 014(4),b=8. 910(5),c=22. 749(5)A ,β=91. 73(3)°,V = 2034 A3,Z=2,Dx=2. 15g·cm-3,λ(MoKa) = 0. 71073A,R=0. 060 for 3107 unique observed reflections (I≥3σ(I)). The complex cation is of one-dimensional chain structure in which the basic unit is a dinuclear complex and the gly-gly ligands are coordinated to metal atoms in two kinds of forms. The overall structure of the dinuclear unit is dioxo and dicarboxyl-bridged.
{(Eu (OOCCH2NHCOCH2NH3) 2 (H2O) 2] (ClO4) 3.2H2O} 2, Mr = 1572, P21 / n, a = 12.014 (4), b = 8. 910 (5), c = 22. 749 (5) A, β = 91. 73 (3) °, V = 2034 A3, Z = 2, Dx = 2.15 g · cm -3, λ (MoKa) = 0. 71073A, R = 0. 060 for 3107 unique observed reflections (I ≥ 3σ (I)). The complex cation is of one-dimensional chain structure in which the basic unit is a dinuclear complex and the gly-gly ligands are coordinated to metal atoms in two kinds of forms The overall structure of the dinuclear unit is dioxo and dicarboxyl-bridged.