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研究了2羟基4仲辛基二苯甲酮肟(N530)与2乙基已基2乙基已基膦酸(HEHEHP)的氯仿溶液,从高氯酸介质中对钯的协同萃取。采用斜率法确定萃合物的组成为:L·Pd·A。协萃反应平衡常数为g K12= 1658,协同萃取配合物的生成常数为β12= 174。计算了协同萃取反应的热力学函数值
The effects of 2-hydroxy-4-secoctyl-benzophenone oxime (N530) and 2-ethylhexyl 2-ethylhexylphosphonic acid (HEHEHP) in chloroform were studied. Synergistic extraction. Using slope method to determine the composition of the extract: L · Pd · A. The reaction equilibrium constant was g K12 = 1658, and the formation constant of the synergistic extraction complex was β12 = 174. The thermodynamic function values of the co-extraction reaction were calculated