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从量子统计处理固体电子状态的费密面和费密球概念出发,对电化学体系中的电极电势的本质进行了讨论。在此基础上说明了电流与费密面附近能态占据情况变化的关系,以及理想极化和理想非极化电极的费密面的特征。电极—电解质溶液界面相的双层结构与电极费密面的结构密切相关。从费密面的特征讨论了零电荷电势。在电化学适用的范围内,费密面近似地用球面来表示。
Starting from the concepts of the Fermi surface and the Fermi sphere of quantum electronic processing of solid states, the nature of the electrode potential in the electrochemical system is discussed. Based on this, the relationship between the current and the occupation of energy states near the Fermi surface and the Fermi surfaces of the ideal and ideal non-polarization electrodes are described. The two-layer structure of the electrode-electrolyte interface phase is closely related to the structure of the electrode facet. The zero charge potential is discussed from the characteristics of the polygons. Fermi surfaces are approximately spherical in the area of electrochemical applicability.