A series of polystyrene resin with C 60 in the side group were prepared by chloromethylation, azidation and cycloaddition. In these C 60 containing polystyrene resins, the C 60 contents are about 2.9% , 6.7% and 11% (mass fraction), respectively. With the increase of C 60 content in the C 60 containing polystyrene resin, the photoconductivity increases obviously. α NP as the charge transport material is better than DMMP, which proves that it is very important that charge transport material(CTM) match the charge generation material(CGM). If no charge transport layer in the photoreceptor exsist, the polystyrene resin with C 60 in the side group could not show any photoconductivity at all. A series of polystyrene resin with C 60 in the side group were prepared by chloromethylation, azidation and cycloaddition. The C 60 contents are about 2.9%, 6.7% and 11% by mass, respectively. With the increase of C 60 content in the C 60 containing polystyrene resin, the photoconductivity increases obviously. Α NP as the charge transport material is better than DMMP, which proves that it is very important that charge transport material (CTM) match the charge generation If (CGM). If no charge transport layer in the photoreceptor exsist, the polystyrene resin with C 60 in the side group could not show any photoconductivity at all.