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根据稳态极化曲线法,恒电位阶跃等电化学方法对氯在石墨-RuO_2阳极上的析出机理进行了分析。实验结果表明氯在RuO_2阳极上的析出反应遵循活化Temkin吸附等温式下的沃尔默-海洛夫斯基反应机理。
The precipitation mechanism of chlorine on graphite-RuO2 anode was analyzed according to steady-state polarization curve and potentiostatic step. The experimental results show that the precipitation of chlorine on the RuO 2 anode follows the Volterra-Herovsky reaction mechanism under the activation Temkin adsorption isotherm.