论文部分内容阅读
合成了一个新的配合物,经元素分析及X-射线衍射对其结构进行了表征.化合物晶体属单斜晶系,P2(1)/c空间群,晶胞参数:a=6.4824(13),b=6.1325(12),c=19.980(4),α=90°,β=91.925(2)°,γ=90°,V=793.8(3)A3,M=245.05,Z=4,Dc=2.050Mg.m-3,F(000)=492,吸收系数μ=1.671mm-1,最终偏离因子R1=0.0263,wR2=0.0692.化合物的分子结构存在一维链状的结构,由于复杂氢键的存在,它的堆积结构呈二维网状排列,而且在[010]方向看到了纳米空洞.
A new complex was synthesized and its structure was characterized by elemental analysis and X-ray diffraction. The crystal of the compound belongs to the monoclinic space group P2 (1) / c, with unit cell parameters: a = 6.4824 (13) B = 6.1325 (12) , c = 19.980 4, α = 90 °, β = 91.925 (2) °, γ = 90 °, V = 793.8 (3) A3, M = 245.05, Z = 4, Dc = 2.050Mg.m-3, F (000) = 492, the absorption coefficient μ = 1.671mm-1, the final deviation factor R1 = 0.0263, wR2 = 0.0692. The molecular structure of the compound exists in one- Due to the existence of complex hydrogen bonds, its stacking structure is arranged in a two-dimensional network, and nano-voids are seen in the direction of [010].