含磷杯芳烃作为一类特殊杯芳烃主体分子,可以通过不同的方式与众多的客体分子作用,形成主体-客体配合物。无论是母体含磷杯芳烃或其配合物都在分子识别、自组装、生物酶模拟、药物设计、化学传感器和金属催化剂的开发等方面显示出广阔的应用潜力。本文综述了近十年来含磷杯芳烃及其配合物的研究进展。对一些新型含磷杯芳烃及其配合物的合成方法与应用作了重点介绍,并展望了研究和发展方向。 Phosphorus calixarene, as a kind of special calixarene host molecule, can interact with a large number of guest molecules in different ways to form host-guest complexes. Both parent phosphorus containing calixarene or its complexes show great potential in molecular recognition, self assembly, enzyme modeling, drug design, chemical sensors and the development of metal catalysts. This review summarizes the research progress of phosphorus-containing calixarenes and their complexes in recent ten years. The synthesis method and application of some new phosphorus-containing calixarene and its complexes are introduced emphatically, and the research and development direction are prospected.