论文部分内容阅读
本文用CNDO/2M对类卡宾二聚(CH_2LiF)_2作了首次量化计算,结果表明这种二聚中间物在特定的构型上具有分离出卡宾之趋势,提出了类卡宾反应活性的理论模型。
In this paper, we first quantified the class of carbene dimer (CH_2LiF) _2 with CNDO / 2M. The results show that this dimerization intermediate has the tendency to separate carbenes in specific configuration, and the theoretical model of carbene-like reaction .