亚铁卟啉络合物因其可逆键合分子氧的性能而受到人们的重视。基于生物体中的亚铁卟啉络合物的轴向位置键合有一定的基团,因而对于铁卟啉及其轴向配位体的研究较为活跃,但有关其催化性能方面的研究报导甚少。 我们制备了以咪唑,2-甲基咪唑,吡啶,4-甲基吡啶为轴向配体的铁卟啉络合物,考察了它们在环已烷定向氧化反应中的催化性能。 Ferrous porphyrin complexes have attracted people’s attention because of their reversible bonding properties of molecular oxygen. Based on the fact that certain groups are bound to the axial position of the ferrous porphyrin complex in living organisms, the research on iron porphyrin and its axial ligand has been relatively active. However, the research reports on its catalytic performance Very few. We prepared iron-porphyrin complexes with imidazole, 2-methylimidazole, pyridine and 4-methylpyridine as axial ligands and investigated their catalytic performance in cyclohexane oxidation.