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通过[PPh4][(mthp S)WS3](mthp=2 methyltetrahydro 2H pyran)和三当量CuBr反应合成了一个新的T型簇合物[PPh4]2[WS4(CuBr)2.6],用单晶X射线衍射方法测定了结构,其二价簇阴离子具有一个由三个铜和一个WS4单元组成的T型WS4Cu3簇结构.
A novel T-type cluster [PPh4] 2 [WS4 (CuBr) 2.6] was synthesized by [PPh4] [(mthp S) WS3] (mthp = 2 methyltetrahydro 2H pyran) and three equivalent CuBr reactions using single crystal X The structure of the structure was determined by the ray diffraction method. The divalent cluster anions have a T-type WS4Cu3 cluster structure composed of three copper and one WS4 unit.