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The method for synthesis of corrected three-wavelengths spectrometers for trace gas components of atmosphere on the basis of development of mathematical model has been suggested. The classification table for possible structures of corrected spectrometers is considered. The synthesis allows to reveal some new variants for development of three-wavelength spectrometers for trace gas components of atmosphere. For experimental checkup of achieved theoretical results, a laboratory pattern of three-wavelength spectrometer is developed and tested.