【摘 要】
：
Reaction of chiral 2,2’-biamino-1,1’-binaphthalene (R or 5) with monosubstituted porphyrin 1b and 2b-c afforded novel chiral diporphyrins 3a-c and 4a-c. Thei
【机 构】
：
Department of Chemistry, Wuhan University, Wuhan, Hubei 430072 , China,Department of Chemistry, Wuha
【出 处】
：
Chinese Journal of Chemistry
论文部分内容阅读
Reaction of chiral 2,2’-biamino-1,1’-binaphthalene (R or 5) with monosubstituted porphyrin 1b and 2b-c afforded novel chiral diporphyrins 3a-c and 4a-c. Their dimetal complexes [(M)2DiPor] have also been prepared. Both structures have been identified by MS, IR, UV-visible, 1H NMR spectra and elemental analysis. These novel chiral compounds show very high optical activities.
Reaction of chiral 2,2’-biamino-1,1’-binaphthalene (R or 5) with monosubstituted porphyrin 1b and 2b-c afforded novel chiral diporphyrins 3a-c and 4a-c. Their dimetal complexes [(M) 2DiPor] Both structures have been identified by MS, IR, UV-visible, 1H NMR spectra and elemental analysis. These novel chiral compounds show very high optical activities.
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