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首次采用氚标记法研究乙炔催化二聚反应机理,结果表明乙炔与Cu(Ⅰ)配位生成中间物同时,伴随乙炔分子上质子向水相转移过程.
The tritium labeling method was used for the first time to study the mechanism of acetylene catalyzed dimerization reaction. The results show that acetylene and Cu (Ⅰ) coordinate to form intermediates, accompanied by the transfer of proton to water phase of acetylene molecules.