超高分子量聚合物胶膜的热拉伸

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The three stages in the hot-dawing process of ultrahigh-molecular-weight polyethylene gel films can be detected by x-ray diffraction, infrared spectroscopy, birefringenece and scanning electron microscopy. In the first stage of the drawing process, the lamellae in the gel films rotate and/or slip with the b-axis preferentially perpendicular to the drawing direction. With increased drawing , the c-axis of the lamellae become parallel to the stretching direction while unfolding of the chain begins, and the chains of the amorphous phases also orient along the drawing direction in the strain-chain domain. When the draw ratio is large enough, the lamellar structure is transformed into a fibrillar structure in a two-dimensional fashion.
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