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High-performance anode is hurdle for on-chip planar microsupercapacitor (MSC).Polypyrrole (PPy) is a highly attractive pseudocapacitive material,but its low cycling stability,and low adhesion with current collector hinder its practicability.Herein we propose one-prong generic strategy to boost the cycling stability of PPy.For our strategy,the electrochemical deposition of multilayered reduced graphene oxide (rGO) on micropatterned Au is utilized,and the resultant rGO@Au pattern is then used for growing highly porous PPy nanostructures by facile electrochemical polymerization.The fabricated PPy anode on rGO@Au has quasi rectangular cyclic voltammetry curves up to-0.7 V and exceptional cycling stability,retaining 82% of capacitance after 10,000 charge/discharge cycles in 2 M KCl electrolyte.The outstanding reliability of PPy on rGO@Au is due to the flexibility of rGO,accommodating structural pulverization and providing a promising background for the nucleation of highly porous nanostructure.Further,an all-polymer based asymmetric aqueous MSC (AMSC) is constructed with PPy anode and PEDOT cathode,which exhibited excellent electrochemical performance compared with conventional symmetric MSCs based on conducting polymers.The constructed AMSC delivered a maximum areal capacitance of 15.9 mF cm-2 (99.3 F cm-3),high specific energy and power densities of 4.3 μWh cm-2 (27.03 mWh cm-3) and 0.36 W cm-2 (0.68 W cm-3) at 1.4 V,respectively.The enhanced electrochemical performances can be illustrated by nucleation mechanism,in which surface topology of rGO generates a promising background for nucleation and electrochemical growth of nanoporous pseudocapacitive conducting polymers with superior interfacial contact and improved surface area.