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Abstract EPR spectra of three new quaternary gadoliniumcomplexes(I: [Gd(C6H5COO)2(NO3)(bipy)]2,Ⅱ : [Gd(m-CH3C6H4COO)2(NO3)(phen)]2 and Ⅲ : [Gd(p-CH3C6H4COO)(NO3)(phen)]2) with mixed anion ligands in polycrystalline powders and solutions have been investig