【摘 要】
：
The title compound(4aR,7aS)-6-benzyl-1-((R)-2-(2-chlorophenyl)-4,5-dihydrothiazole-4-carbonyl)-hexahydro-5H-pyrrolo[3,4-b]pyridine-5,7(6H)-dione(C24H22ClN3O3S)w
【机 构】
：
College of Horticulture and Landscape Architecture,Tianjin Agricultural University,Tianjin 300384,Ch
论文部分内容阅读
The title compound(4aR,7aS)-6-benzyl-1-((R)-2-(2-chlorophenyl)-4,5-dihydrothiazole-4-carbonyl)-hexahydro-5H-pyrrolo[3,4-b]pyridine-5,7(6H)-dione(C24H22ClN3O3S)was synthesized,and its chemical structure was confirmed by 1H NMR,13C NMR and single-crystal X-ray diffraction.The crystal of the title compound belongs to monoclinic system,space group C2/c with a = 28.929(6),b = 7.858(16),c = 22.936(5)?,β = 125.20(3)°,V = 4221.4(15)?3,Z=8,Dc = 1.473 g/cm3,μ(MoKa)= 0.314 mm-1,the final R = 0.0629 and wR = 0.1708 for 2812 observed reflections with I＞2σ(I).The preliminary insecticidal activity indicated that the title compound exhibited good and promising insecticidal activities against Mythimna separata,Plutella xylostella and C u lex pipiens pallens.Moreover,the calcium imaging experiment indicated that the title compound can activate intracellular calcium channels to release the stored calcium ion from endoplasmic reticulum(ER)to cytoplasm of Mythimna separata.
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