关于干酪根热降解反应动力学参数测定的实验模拟方法和机理的探讨,李执等人已有详细论述,这里主要把干酪根热降解反应动力学参数的数值方法的最优化计算,作一介绍和探讨。 不同类型和结构的干酪根所测得的动力学参数是不相同的,在数学上,就是求解带约束的最优化问题。关于构成最优化问题模型是:求解的变量(参数)、目标函数和约束条件。对设计变量的选择、目 On kerogen thermal degradation reaction kinetic parameters of the experimental simulation method and mechanism of discussion, Li Zhi et al. Have been discussed in detail, mainly to kerogen thermal degradation kinetic parameters of the numerical method for optimal calculation, made an introduction And explore. Kinetic parameters measured by kerogen of different types and structures are not the same, and mathematically, it is the optimization problem with constraint. The models that make up the optimization problem are: Solved variables (parameters), objective functions, and constraints. The choice of design variables, head