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系统研究了所合成的七个8-氨基喹琳-5-偶氮苯类和三个8-(对甲苯磺酸氨基)喹啉-5-偶氮苯类新衍生物与Co(Ⅱ)的显色和荧光反应。发现了试剂取代基对配合物显色增敏和荧光增感的规律,探讨了H_2O_2对荧光增感的机理。
The synthesis of seven novel 8-aminoquinoline-5-azobenzenes and three novel derivatives of 8- (p-toluenesulfonamido) quinoline-5- Color reaction and fluorescence. The rules of sensitization and fluorescence sensitization to the complex were found, and the mechanism of fluorescence sensitization of H_2O_2 was discussed.