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综述了以过氧化氢为氧源,多金属氧酸盐催化烯烃环氧化的研究进展,尤其是针对基于多金属氧酸盐的反应控制相转移催化体系近年来的研究进展进行了详细阐述.“,”This review summarizes recent developments for the epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates.Especially,reaction-controlled phase transfer catalysis based on polyoxometalates for epoxidation of olefins has been described in detail.