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近期,我们集中研究了金属羰基化合物氧转移反应的动力学和机理 ,这项研究的重要应用背景之一是合成特殊的金属有机化合物.合成的关键步骤是起始物中部分羰基配体被氧转移试剂湮灭生成配位不饱和中间体“M·Solvent”,后者再与选定配体或E结合得到目标化合物.
Recently, we have focused on the kinetics and mechanism of the oxygen transfer reaction of metal carbonyls. One of the important applications of this study is the synthesis of special metal organic compounds. The key step of the synthesis is to oxidize some of the carbonyl ligands in the starting material to oxygen The transfer reagent annihilation generates the coordination unsaturated intermediate “M · Solvent”, which in turn binds with the selected ligand or E to give the target compound.