Element enrichment and U-series isotopic characteristics of the hydrothermal sulfides at Jade site i

来源 :Science in China(Series D:Earth Sciences) | 被引量 : 0次 | 上传用户:xtopg
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The geochemical and U-series isotopic characteristics of hydrothermal sulfide samples from the Jade site (127°04.5′E, 27°15′N, water depth 1300-1450 m) at Jade site in the Okinawa Trough were analyzed. In the hydrothermal sulfide samples bearing sulfate (samples HOK1 and HOK2), the LREEs are relatively enriched. All the hydrothermal sulfide samples except HOK1 belong to Zn-rich hydrothermal sulfide. In comparison with Zn-rich hydrothermal sulfides from other fields, the contents of Zn, Pb, Ag, Cd, Au and Hg are higher, the contents of Fe, Al, Cr, Co, Ni, Sr, Te, Cs, Ti and U lower, and the 210Pb radioactivity ratios and 210Pb/Pb ratios very low. In the hydrothermal sulfide mainly composed of sphalerite, the correlations between rare elements Hf and U, and Hf and Mn as well as that between dispersive elements Ga and Zn, are strongly positive; also the contents of Au and Ag are related to Fe-sulfide, because the low temperature promotes enrichment of Au and Ag. Meanwhile, the positive correlations between Fe and Bi and between Zn and Cd are not affected by the change of mineral assemblage. Based on the 210Pb/Pb ratios of hydrothermal sulfide samples (3.99×10-5-5.42×10?5), their U isotopic composition (238U content 1.15-2.53 ppm, 238U activity 1.07-1.87 dpm/g, 234U activity 1.15-2.09 dpm/g and 234U/238U ratio 1.07-1.14) and their 232Th and 230Th contents are at base level, and the chronological age of hydrothermal sulfide at Jade site in the Okinawa Trough is between 200 and 2000 yr. The geochemical and U-series isotopic characteristics of hydrothermal sulfide samples from the Jade site (127 ° 04.5’E, 27 ° 15’N, water depth 1300-1450 m) at the Jade site in the Okinawa Trough were analyzed. In the hydrothermal sulfide All of the hydrothermal sulfide samples except HOK1 belong to Zn-rich hydrothermal sulfide. In the case of Zn-rich hydrothermal sulfides from other fields, the contents of Zn, Pb, Ag, Cd, Au and Hg are higher, the contents of Fe, Al, Cr, Co, Ni, Sr, Te, Cs, Ti and U lower, and the 210Pb radioactivity ratios and 210Pb / Pb ratios very low. In the hydrothermal sulfide mainly composed of sphalerite, the correlations between rare elements Hf and U, and Hf and Mn as well as that between dispersive elements Ga and Zn, are strongly positive; also the contents of Au and Ag are related to Fe-sulfide, because the low temperature intuitive enrichment of Au and Ag. Meanwhile, the posit ive correlations between Fe and Bi and between Zn and Cd are not affected by the change of mineral assemblage. Based on the 210Pb / Pb ratios of hydrothermal sulfide samples (3.99 × 10-5-5.42 × 10-5), their U isotopic composition (238U content 1.15-2.53 ppm, 238U activity 1.07-1.87 dpm / g, 234U activity 1.15-2.09 dpm / g and 234U / 238U ratio 1.07-1.14) and their 232Th and 230Th contents are at base level, and the chronological age of hydrothermal sulfide at Jade site in the Okinawa Trough is between 200 and 2000 yr.
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