【摘 要】
：
A novel complex, [Cu 2(phen)(sal)(Hsal) 2] n(1), was synthesized and structurally characterized. The basic dimeric units are hold by sal ligands and extende
【出 处】
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Chinese Journal of Chemistry
论文部分内容阅读
A novel complex, [Cu 2(phen)(sal)(Hsal) 2] n(1), was synthesized and structurally characterized. The basic dimeric units are hold by sal ligands and extended into 1-D network. The carboxylate groups of salicylates coordinate to the central ion in three different coordination modes: chelating, bridging and bridging-chelating. In the case of bridging-chelating of the carboxylate group of the salicylate, all three oxygen atoms of salicylate are bidentately coordinated to copper ion, namely, μ 4-η 3 binding mode.
A novel complex, [Cu 2 (phen) (sal) (Hsal) 2] n (1), was synthesized and structurally characterized. The basic dimeric units are hold by sal ligands and extended into 1-D network. The carboxylate groups of salicylates coordinate to the central ion in three different coordination modes: chelating, bridging and bridging-chelating. In the case of bridging-chelating of the carboxylate group of the salicylate, all three oxygen atoms of salicylate are bidentately coordinated to copper ion, namely, μ 4-η 3 binding mode.
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