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介绍了不同类型的过渡金属离子的大二环笼状配合物合成方法的研究进展 .重点介绍了 N,S给予体过渡金属离子 (特别是钴 )的大二环笼状配合物的研究进展 ,以及 S3N3,S4N2 ,N3Se3 给予体原子大二环笼状配合物的合成方法的研究进展
The research progress on the synthesis of macrocyclic dinuclear complexes with different types of transition metal ions is reviewed.The research progress of macrocyclic dinuclear complexes with N, S donor transition metal ions (especially cobalt) As well as the research progress of the synthetic methods for the large bicyclic ring complexes of S3N3, S4N2 and N3Se3