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以(R,R)-N,N′-[2,2′-双(次氨基次甲基)]双[4-(亚甲基-N-吗啉基)-6-叔丁基)苯酚]-1,2-二苯基乙二胺为配体合成了6种SalenCoX配合物,其轴向离子分别为氯、溴、硝酸根、叠氮根、三氟醋酸根及四氟化硼根。利用1HNMR、13CNMR、FT-IR、UV-Vis、循环伏安法、ESI-MS和元素分析对配体及配合物进行了表征,证明了所得产物与目标化合物一致。
(R, R) -N, N’- [2,2’-bis (nitrilotrimethyl)] bis [4- (methylene- N -morpholino) -6-t- butyl) phenol ] -1,2-diphenylethylenediamine as ligands, six kinds of SalenCoX complexes were synthesized. Their axial ions were chlorine, bromine, nitrate, azide, trifluoroacetate and boron tetrafluoride . The ligands and their complexes were characterized by 1HNMR, 13CNMR, FT-IR, UV-Vis, cyclic voltammetry, ESI-MS and elemental analysis. The results showed that the obtained products were consistent with the target compounds.