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利用高压DSC研究了含能材料二缩三乙二醇二硝酸酯(TEGDN)的热分解特性,结果表明:常压下,TEGDN 有一个分解放热峰,没有吸热峰;当压力为2MPa 时,此峰的峰形变得尖锐,峰温后移了5℃左右,放热量增加了一倍还多;压力再增大,则峰形、峰温、放热量的变化均不显著。通过研究获得了TEGDN 的动力学参数,对TEGDN分解机理也进行了分析讨论
The thermal decomposition of TEGDN was studied by high pressure DSC. The results showed that TEGDN had a decomposition exothermic peak at atmospheric pressure without endothermic peak. When the pressure was 2 MPa , The peak shape of this peak becomes sharp, the peak temperature after the shift of 5 ℃, the heat more than doubled; pressure and then increase, the peak shape, peak temperature, exothermic changes are not significant. By studying the kinetic parameters of TEGDN, the mechanism of TEGDN decomposition was also discussed