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The title complex, C22H22MnN5O2, crystallizes in orthorhombic system, space group P212121 with a = 6.887(1), b = 11.718(2), c = 25.721(5) ? V = 2075.7(7) 3, Z = 4, Mr = 443.39, F(000) = 920, Dc = 1.419 g/cm3 and m = 0.665mm-1 (MoKa). The structure was refined to R = 0.0593 and wR = 0.1427 for 3576 observed reflections with I ≥ 2s(I). The Mn(Ⅲ) atom is coordinated to one bzan2- [bzan2- = N, N-ethylenebis(benzoylacetoneiminato)] ligand binding in the equatorial mode and two N3- ions in the axial positions. The azide acts as a trans--(1, 3) bridge, resulting in an infinite helical chain propagating along the b axis.
The title complex, C22H22MnN5O2, crystallizes in orthorhombic system, space group P212121 with a = 6.887 (1), b = 11.718 (2), c = 25.721 443.39, F (000) = 920, Dc = 1.419 g / cm3 and m = 0.665 mm-1 (MoKa). The structure was refined to R = 0.0593 and wR = 0.1427 for 3576 at reflections with I ≥ 2s (I). The Mn (III) atom is coordinated to one bzan2- [bzan2- = N, N-ethylenebis (benzoylacetoneiminato)] ligand binding in the equatorial mode and two N3- ions in the axial positions. The azide acts as a trans - ( 1, 3) bridge, resulting in an infinite helical chain propagating along the b axis.