A near-infrared phosphorescent probe for F- based on a cationic iridium(III) complex with triarylbo

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在这个工作,一在红外线附近( NIR )为 F 的发磷光的探查基于 cationic 红外( III )建筑群[红外( Bpq ) 2 ( quqo )]有 dimesitylboryl ( Mes2B )的 PF6 ( 1 )在 cyclometalated CN 上组织 ligands ( Bpq )和2-( quinolin-2-yl ) quinoxaline ( quqo )作为 NN ligand 被设计并且综合。1 的激动的州的性质用分子的轨道的计算和试验性的方法详细被调查。在刺激之上,
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