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本文的目的是:[Ⅰ]通过自由基交换反应的实例,以诱导效应指数为纲,将某些关系式联系起来,并藉此阐明自由基和分子的活性与其结构的关系;[Ⅱ]探讨谢苗诺夫对波兰衣公式提出的几个问题,(?)值以及A与(?)的关系,并总结出E、q、A、(?)值变化的规律性;[Ⅲ]说明如何利用上述各种关系式和各量的变化规律性,根据分子自由基的结构,来确定它们的相对电负性、活性等的次序和计算它们的键能、反应热、活化能,比速度等的值。
The purpose of this paper is to: [I] link some of the relationships by taking the example of free radical exchange reactions as the key link, and to elucidate the relationship between the activity and the structure of free radicals and molecules; [II] The problem, the value of (?), And the relation between A and (?) Raised by Semenov on the Polish clothing formula and the regularity of the change of the values of E, q, A and Using the relationship between the above and the variation of the amount, according to the molecular structure of free radicals to determine their relative electronegativity, activity and other order and to calculate their bond energy, reaction heat, activation energy, specific speed The value of.