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合成了一种新的水溶性羰基四对磺基苯基卟啉钙(Ⅱ)[Ru(CO)TPPS]配合物,测定了电子光谱、红外光谱、核磁共振谱,进行了元素分析。对前人合成TPPS及Pu_3(CO)_(12)的方法进行了一定程度的改进。对合成Ru(CO)TPPS的实验条件进行了探讨。
A new water - soluble calcium tetrakis (p - sulfophenyl) porphyrin calcium (Ⅱ) [Ru (CO) TPPS] complex has been synthesized and its electronic spectra, IR spectra and NMR spectra have been determined. The previous methods of synthesizing TPPS and Pu_3 (CO) _ (12) have been improved to a certain extent. The experimental conditions for the synthesis of Ru (CO) TPPS were discussed.