Carbon-based material has been regarded as one of the most promising electrode materials for potassium-ion batteries (PIBs).However,the battery performance based on reported porous carbon electrodes is still unsatisfactory,while the in-depth K-ion storage mechanism remains relatively ambiguous.Herein,we propose a facile “in situ self4emplate bubbling” method for synthesizing interlayer-tuned hierarchically porous carbon with different metallic ions,which delivers superior K-ion storage performance,especially the high reversible capacity (360.6 mAh.g-1@0.05 A.g-1),excellent rate capability (158.6 mAh.g-1@10.0 A.g-1) and ultralong high-rate cycling stability (82.8％ capacity retention after 2,000 cycles at 5.0 A.g-1).Theoretical simulation reveals the correlations between interlayer distance and K-ion diffusion kinetics.Experimentally,deliberately designed consecutive cyclic voltammetry (CV)measurements,ex situ Raman tests,galvanostatic intermittent titration technique (GITT) method decipher the origin of the excellent rate performance by disentangling the synergistic effect of interlayer and pore-structure engineering.Considering the facile preparation strategy,superior electrochemical performance and insightful mechanism investigations,this work may deepen the fundamental understandings of carbon-based PIBs and related energy storage devices like sodium-ion batteries,aluminum-ion batteries,electrochemical capacitors,and dual-ion batteries.