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Three new supramolecular polymers, [(IP)(H_2SO_4)(H_2O)](1), [(H_2SDC)(BPA)](2) and [Mn(SDC)(IP)_2]_n (3), have been constructed by three modes(rigid IP, rigid SDC + flexible BPA, rigid IP + rigid SDC). Polymers 1 and 2 are supramolecular structures, asse