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INTRODUCTION. In our attempts of chemical simulation of the active center of nitrogenase we have been interested in the reaction system of various ferrous thiolates with thiomolybdatee. In previous papers, we have reported the syntheses of ferrous monodentothiolates and their reactions with tetrathiomolybdate. The possible structure type of ferrous thiolates when bidentothiols are used inspired our interest in this work.
INTRODUCTION. In our attempts of chemical simulation of the active center of nitrogenase we have been interested in the reaction system of various ferrous thiolates with thiomolybdatee. In previous papers, we have reported the syntheses of ferrous monodentothiolates and their reactions with tetrathiomolybdate. The possible structure type of ferrous thiolates when bidentothiols are used inspired our interest in this work.