总结了我们在新型炔银簇化合物研究方面的最新进展.这些化合物分为以下几种类型:(a)1,3,5-己三炔基和1,3,5,7-辛四炔基;(b)1,5-己二炔基;(c)经膦酸配体组装的乙炔基和烷基乙炔基;(d)苯乙炔基、环烷基乙炔基和含氮杂环基乙炔基结构单元的银簇化合物;(e)经不同类型的银-碳配位键连接,并进一步通过分子内/分子间作用力稳固其配位网络的炔银化合物.我们还进一步讨论了溶剂、配体的位阻大小和辅助配体类型对于多维配位网络结构的影响. The recent advances in the research of new alkyne silver clusters have been summarized.These compounds are divided into the following categories: (a) 1,3,5-hexatriynyl and 1,3,5,7-octa-tetra-nynyl ; (b) 1,5-hexadiynene; (c) ethynyl and alkylethynyl groups assembled by phosphonic acid ligands; (d) phenylethynyl, cycloalkylethynyl and nitrogen- (E) alkyne silver compounds that are linked by different types of silver-carbon coordination bonds and further stabilize their coordination network by intermolecular / intermolecular forces We further discuss the use of solvents, The size of the steric hindrance and the type of ancillary ligands affect the structure of the multidimensional coordination network.