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含硫氮双齿配位基的有机硅聚合物和三氯化铑反应，制备了聚－γ－Ｎ（β－丁硫基）乙基胺丙基硅氧烷铑络合物和聚－γ－Ｎ（β－苯硫基）乙基胺丙基硅氧烷铑络合物．选用Ｉ－癸烯，Ｉ－十二烯、苯基烯丙醚、苯丙烯、甲基丙烯酸丁酯、环己烯、氯代十一烯和三乙氧基硅烷进行硅氢加成反应，另用丁烯进行氢化，以其实验结果评价其催化活性．实验结果表明两种铑络合物具有良好的催化活性，在１．５～１．８ｈ之内，含有４．９×１０－６ｍｏｌ的两种铑络合物可将Ｉ－癸烯，苯基烯丙基醚，Ｉ－十二烯硅氢化７８％以上．其选择性在９６％～１００％之间．对丁烯的氢化效果良好．
Polymers of poly-γ-N (β-butylthio) ethylaminopropylsiloxane rhodium complex and poly-γ were prepared by reaction of the organosilicon polymer containing sulfur and nitrogen bidentate ligand with rhodium trichloride -N (β-phenylthio) ethylaminopropylsiloxane rhodium complex. I-decene, I-dodecene, phenyl allyl ether, styrene-propylene, butyl methacrylate, cyclohexene, chlorinated undecene and triethoxysilane hydrosilylation reaction, the other Hydrogenation with butene was used to evaluate its catalytic activity based on the experimental results. The experimental results show that the two rhodium complexes have good catalytic activity. Within 1.5 ~ 1.8h, the two rhodium complexes containing 4.9 × 10-6mol can convert I-decene, phenyl Allyl ether, I-dodecene hydride 78% or more. Its selectivity is between 96% and 100%. The hydrogenation of butene is good.