红外光谱法研究LB膜中的分子取向

来源 :物理化学学报 | 被引量 : 0次 | 上传用户:dingyi203
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The structure information of orientation and packing of molecular chains can be ob-tained from infrared transmission and reflection-absorbance (RA) spectra. In the present paper, on the basis of Umemura et al., their FORTRAN program of minicomputer was developed and can be run on 486 personal computer. By colnparison of infrared transmission and RA intensities, surface enhancement factors and molecular orientation angle were calculated using the above program, and the influence of complex refractive index, angle of incidence, and thickness of LB film were discussed. These results are consistent with that of Umemura et al. The structure information of orientation and packing of molecular chains can be ob-tained from infrared transmission and reflection-absorbance (RA) spectra. In the present paper, on the basis of Umemura et al., Their FORTRAN program of minicomputer was developed and can By run on 486 personal computer. By colnparison of infrared transmission and RA intensities, surface enhancement factors and molecular orientation angle were calculated using the above program, and the influence of complex refractive index, angle of incidence, and thickness of LB film were discussed. These results are consistent with that of Umemura et al.
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