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用平衡吸附法研究了湖北省5种类型土壤对K+的吸附特征,探讨了溶液K+浓度、pH值及离子强度对土壤吸附K+的影响。结果表明:(1)土壤对K+的吸附量随溶液中K+浓度升高而增加,支持电解质的阳离子可同时被吸附,对K+吸附的机制有电性作用和矿物对K+的选择性吸附;(2)pH值升高,K+的吸附量增加,在供试pH范围内,增幅为21.3%~40.2%,单位pH变化对K+吸附量的影响为0.59~1.43mmol/kg;(3)离子强度由0.01增至0.20时,K+吸附量降低22.5%~55.4%;(4)以上因子的影响程度因土壤而明显不同,主要取决于其矿物组成和表面电荷性质。
The adsorption characteristics of K + in five types of soils in Hubei Province were studied by equilibrium adsorption. The effects of K + concentration, pH value and ionic strength on K + adsorption were discussed. The results showed that: (1) The amount of K + adsorbed by the soil increased with the increase of K + concentration in the solution, the cation of the supporting electrolyte could be adsorbed at the same time, and the K + adsorption mechanism and the mineral selective adsorption of K + 2) The increase of pH value and the increase of K + adsorption amount increased by 21.3% -40.2% in the range of test pH, and the influence of unit pH value on the amount of K + adsorption was 0.59-1.43 mmol / kg; (3) K + adsorption decreased by 22.5% -55.4% when the ionic strength increased from 0.01 to 0.20; (4) The influence degree of the above factors was obviously different due to soil, which mainly depended on Mineral composition and surface charge properties.