主客配位笼状超分子的激发态动力学全时尺度瞬态光谱揭示核壳电荷迁移

来源 :第十五届全国化学动力学会议 | 被引量 : 0次 | 上传用户：pengyechao

【摘要】

：

本研究工作利用稳态的吸收和发射光谱结合时间分辨光谱技术,定量地给出了一种笼状超分子(CC）的激发态光物理特性,通过DFT/TDDFT量子化学计算的手段,我们发现CC 存在一种新型可

【作者】

：

杨阳韩克利

【机构】

：

中国科学院大连化学物理研究所分子反应动力学国家重点实验室,辽宁省大连市沙河口区中山路457号,116023

【出处】

：

第十五届全国化学动力学会议

【发表日期】

：

2017年8期

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本研究工作利用稳态的吸收和发射光谱结合时间分辨光谱技术,定量地给出了一种笼状超分子(CC）的激发态光物理特性,通过DFT/TDDFT量子化学计算的手段,我们发现CC 存在一种新型可见光触发的内核coronene向外壳cage的电荷转移过程,我们命名为core-to-cage charge transfer(CCCT).

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主客配位笼状超分子的激发态动力学全时尺度瞬态光谱揭示核壳电荷迁移

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